Version 1.0, August 31, 2001, Copyright, Hugh Jack 1993-2001

2.6.1.2 - Periodic Table

A.Metallic elements

1.1 to 3 valence electrons

2.Electropositive - tend to give up electrons in bonding

B.Non-metals

1.1 to 3 electrons short of full valence level

2.Electronegative - tend to add electrons in bonding

C.Intermediate elements

1.Metallic and non-metallic characteristics

2.Includes semiconductors

3.May gain or lose electrons in bonding

III.Atomic Bonding

A.Bonding Reactions

1.Bonding forces

a.Attractive force due to bond

b.Repulsive force due to electron clouds

c.Equilibrium when net force is zero

2.Bonding Energy - Equilibrium when energy is minimum

B.Primary (Strong) Bonding

1.Ionic

a.Transfer of electrons from electropositive to electronegative atoms

b.Coulombic attraction between ions

2.Covalent

a.Sharing of electrons between 2 (or a few) atoms

b.Number of bonds are those needed to fill valence level

c.Bonds between atoms with similar electronegativities

3.Metallic

a.Sharing of electrons among many atoms

b.Valence electrons 'free' to move

c.Weak (Secondary) Bonding

4.Induced Dipole

a.Temporary, short term shifts in charge creating dipoles

b.Coulombic attraction between dipoles

5.Polar Molecules

a.Permanent dipoles

b.Large differences in attraction for electrons

c.Coulombic attraction between dipoles

6.Hydrogen Bonding

a.Special case of polar molecule bonding

b.Dipoles formed between Hydrogen and highly electronegative atoms (e.g. H2O)